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Chord diagram for Asus4
Chord diagram for D
Chord diagram for A
Chord diagram for G
Chord diagram for Em
      Standard tuning, capo on 3rd fret.

I'm not sure how accurate it is. Power chords and major/minor chords both work. 
But I use all open chords and I think Asus4 can be used as well instead of A major.

    Asus4
e|---0---|
B|---3---|
G|---2---|
D|---2---|
A|---0---|
E|-------|


Intro is same as verse

        D              A
You can pray all day to Satan
        G           A
You can drive pretty fast
        D              A
You can drink with your prescriptions
        G            A
But it never comes to pass

  G             A
I know you don't believe me
           D                G
But you're gonna see, you're gonna see
A
One hundred and three

You can make marks with a razor
Choke out on the bed
But do you feel a sense of failure
When you just can't end up dead?

I know you don't believe me
But you're gonna see, you're gonna see
One hundred and three

G  G/F#    Em                A
How can I get it through to you?
  G         G/F#         Em
I just don't think your death wish
   A              G         D (this is the same chord that leads to the outro)
Is gonna come, is gonna come true

D A G A
(outro riff)

End on D
    

Source: https://tabs.ultimate-guitar.com/tab/the_pains_of_being_pure_at_heart/103_chords_1415792

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